Not sure where you got the 34.5c reading for 13th September 2016 from? It reached 32.1c that day according to the Heathrow records.
I posted this same article on NW - it is an interesting conversation. My opinion is that Heathrow has a number of factors in its favour - it is in the SE of England (hottest area of the country), it is within Greater London so benefits from the UHI effect, it is far enough away from the south coast, the east coast and the Thames Estuary so is an inland location.
As the article states, however, there is very little difference between the Heathrow records and Kew, which is a centrally located weather station in London, and is actually very similar to St James's Park in central London and Northolt in NW London just up the road from Heathrow.
It's not actually all that surprising it often tops the table for hottest temperatures. it's in the warmest part of the country in summer, it's located within the boundaries of the biggest city in the UK by far and is sheltered from cooling sea breezes.
Originally Posted by: danm